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Moon, Hoi Ri
Functional Inorganic Nanomaterials for Energy Lab (FINE)
Research Interests
  • Inorganic-organic hybrid materials, carbon capture materials, hydrogen storage materials, heterogeneous catalyst

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A comparison of the H-2 sorption capacities of isostructural metal-organic frameworks with and without accessible metal sites: [{Zn-2(abtc)(dMf)(2)}(3)] and [{Cu-2(abtc)(dMf)(2)}(3)] versus [{Cu-2(abtc)}(3)]

Cited 149 times inthomson ciCited 156 times inthomson ci
Title
A comparison of the H-2 sorption capacities of isostructural metal-organic frameworks with and without accessible metal sites: [{Zn-2(abtc)(dMf)(2)}(3)] and [{Cu-2(abtc)(dMf)(2)}(3)] versus [{Cu-2(abtc)}(3)]
Author
Lee, Yong-GonMoon, Hoi RiCheon, Young EunSuh, Myunghyun Paik
Issue Date
2008
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.47, no.40, pp.7741 - 7745
Abstract
The isostructural metal-organic frameworks [{Zn2(abtc)(dmf) 2}3] (1a), [{Cu2(abtc)(dmf)2} 3] (2a), and [{Cu2(abtc)}3] (2b; H 4abtc = 1,1′-azobenzene-3,3′,5,5′-tetracarboxylic acid) have high sorption capacities for H2, N2, CO 2, and CH4. Solid 2b, which has accessible metal sites (AMSs), has a higher H2 adsorption capacity than 1a or 2a (see picture; T = 77 K), neither of which have AMSs, because of its lower molecular weight and greater isosteric heat of H2 adsorption.
URI
https://scholarworks.unist.ac.kr/handle/201301/8459
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=54749126111
DOI
10.1002/anie.200801488
ISSN
1433-7851
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CHM_Journal Papers
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