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BielawskiChristopher W

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Dihaloimidazolidinediones as Versatile Halodehydrating Agents

Author(s)
Moerdyk, Jonathan P.Bielawski, Christopher W.
Issued Date
2014-10
DOI
10.1002/chem.201403407
URI
https://scholarworks.unist.ac.kr/handle/201301/8421
Citation
CHEMISTRY-A EUROPEAN JOURNAL, v.20, no.42, pp.13487 - 13490
Abstract
Dihaloimidazolidinediones containing geminal dibromides, dichlorides, or diiodides were synthesized and used to transform various alcohols to their corresponding alkyl halides in high yields and under mild conditions. High functional group tolerance and, in many cases, high selectivities were observed. Efforts toward elucidating the mechanism revealed that significant charge build-up may occur at the eventual halogen containing carbon nucleus prior to substitution.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
0947-6539

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