Defect engineering to accelerate charge transport in LaFeO3 photocathodes via thermal oxidation: A combined experimental and theoretical study

Abstract

In order to improve poor charge carrier transport properties of p-type oxide semiconductors, the post thermal treatment under oxygen atmosphere is systematically studied as a defect engineering strategy for LaFeO3 photocathodes. The post-thermal oxidation process significantly decreases the photo-generated charge recombination and promotes the charge transport properties of LaFeO3 photocathodes. The density functional theory calculations and experimental analyses indicate that the thermal oxygen treatment can promote the formation of La vacancy and the reduction of the oxygen vacancy in LaFeO3, which facilitates its bulk charge transport by increasing hole carrier density. The optimized LaFeO3 photocathode yields an O-2 reduction photocurrent density of -313 mu A/cm(2) at 0.6 V vs RHE in O-2-saturated KOH solution under 1 sun irradiation. Additionally, we also investigated the feasibility of photoreduction of water by using a Pt-deposited LaFeO3 photocathodes.