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Kim, BongSoo
Polymer & Organic Semiconductor Lab.
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Halogenated 9H-Indeno[1,2-b]Pyrazine-2,3-Dicarbonitrile End Groups Based Asymmetric Non-Fullerene Acceptors for Green Solvent-Processable, Additive-Free, and Stable Organic Solar Cells

Author(s)
Gopikrishna, PeddaboodiChoi, HuijeongKim, Do HuiLee, DongchanHwang, Jun HoJin, Seon-MiLee, EunjiCho, ShinukKim, BongSoo
Issued Date
2024-04
DOI
10.1002/smll.202401080
URI
https://scholarworks.unist.ac.kr/handle/201301/82291
Citation
SMALL, pp.2401080
Abstract
Non-fullerene acceptors (NFAs) significantly enhance photovoltaic performance in organic solar cells (OSCs) using halogenated solvents and additives. However, these solvents are environmentally detrimental and unsuitable for industrial-scale production, and the issue of OSCs' poor long-term stability persists. This report introduces eight asymmetric NFAs (IPCnF-BBO-IC2F, IPCnF-BBO-IC2Cl, IPCnCl-BBO-IC2F, and IPCnCl-BBO-IC2Cl, where n = 1 and 2). These NFAs comprise a 12,13-bis(2-butyloctyl)-3,9-diundecyl-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno-[3,2-b]indole (BBO) core. One end of the core attaches to a mono- or di-halogenated 9H-indeno[1,2-b]pyrazine-2,3-dicarbonitrile (IPC) end group (IPC1F, IPC1Cl, IPC2F, or IPC2Cl), while the other end connects to a 2-(5,6-dihalo-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile (IC) end group (IC2F or IC2Cl). The optical and electronic properties of these NFAs can be finely tuned by controlling the number of halogen atoms. Crucially, these NFAs demonstrate excellent compatibility with PM6 even in o-xylene, facilitating the production of additive-free OSCs. The di-halogenated IPC-based NFAs outperform their mono-halogenated counterparts in photovoltaic performance within OSCs. Remarkably, the di-halogenated IPC-based NFAs maintain 94-98% of their initial PCEs over 2000 h in air without encapsulation, indicating superior long-term device stability. These findings imply that the integration of di-halogenated IPCs in asymmetric NFA design offers a promising route to efficient, stable OSCs manufactured through environmentally friendly processes.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1613-6810
Keyword (Author)
additive-freeasymmetric non-fullerene acceptorsgreen solventhalogenated 9H-indeno[1,2-b]pyrazine-2,3-dicarbonitrileorganic solar cellspower conversion efficiency
Keyword
NONFULLERENE ACCEPTORHIGH-PERFORMANCEEFFICIENCYENABLES

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