In this study, 2-D simulation was performed using C1, GRI3.0 and SD mechanisms to predict the auto-ignition of syngas. However, unlike the experimental results, auto-ignition was not predicted at temperature below 940 K. In order to solve this problem, chemical mechanism was modified by through various analysis. Auto-ignition was predicted in low temperature region through the modified mechanism. In addition, the modified mechanism was verified using ignition delay time, flame speed and CEMA.