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Biocatalyzed Artificial Photosynthesis by Hydrogen-Terminated Silicon Nanowires

Author(s)
Lee, Hwa YoungRyu, JungkiKim, Jae HongLee, Sahng HaPark, Chan Beum
Issued Date
2012-11
DOI
10.1002/cssc.201200251
URI
https://scholarworks.unist.ac.kr/handle/201301/6905
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84869422235
Citation
CHEMSUSCHEM, v.5, no.11, pp.2129 - 2132
Abstract
Down to the wires: A highly efficient artificial photosynthetic system employing hydrogen-terminated silicon nanowires is reported. The nanowires enable a cascading electron transfer from electron donor to NAD+ via a rhodium-based electron mediator. Approximately 80 % of NADH is photoregenerated from NAD+ by the nanowires during 2 h of light irradiation, and successfully coupled with the photoenzymatic synthesis of L-glutamate.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1864-5631
Keyword (Author)
artificial photosynthesisbiocatalysislight-harvesting materialsnanowiressilicon
Keyword
NICOTINAMIDE COFACTOROPTICAL-PROPERTIESENERGY-CONVERSIONVISIBLE-LIGHTREGENERATIONEFFICIENTSURFACESSPECTROSCOPYPHOTOCATHODEREDUCTION

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