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Jang, Ji-Hyun
Nano Crystal Lab (NCL)
Research Interests
  • Graphene, photoelectrochemical (PEC) H2 generation, ORR/OER, SERS,3D-Nanostructures, supercapacitors, thermoelectric materials

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Chemically amplified resists based on poly(1,4-dioxaspiro[4.4]nonane-2-methyl methacrylate)

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Title
Chemically amplified resists based on poly(1,4-dioxaspiro[4.4]nonane-2-methyl methacrylate)
Author
Kim, JBPark, JJJang, Ji-Hyun
Keywords
Chemically amplified resist; Ketal-protected polymer; Poly(1,4-dioxaspiro[4.4]nonane-2-methyl methacrylate)
Issue Date
2000-01
Publisher
ELSEVIER SCI LTD
Citation
POLYMER, v.41, no.1, pp.149 - 153
Abstract
The present paper describes a novel class of ketal-protected chemically amplified photoresists. Poly(1,4-dioxaspiro[4.4]nonane-2-methyl methacrylate) (poly(DNMMA)) was synthesized and evaluated as a matrix polymer. The ketal group of the polymer hydrolyzes under acid catalysis to give two alcohol functionalities and a cyclopentanone. The ketal polymer is insoluble in an aqueous developer, while the hydrolyzed products are soluble. The decomposition temperature in the presence of acid was below room temperature. The polymer has high transparency in the deep UV region and its absorbances were 0.015 μm-1 at 248 nm and 0.163 μm-1 at 193 nm. The existence of the generated cyclopentanone after deprotection improves sensitivity by increasing acid diffusion. The present paper describes a novel class of ketal-protected chemically amplified photoresists. Poly(1,4-dioxaspiro[4.4]nonane-2-methyl methacrylate) (poly(DNMMA)) was synthesized and evaluated as a matrix polymer. The ketal group of the polymer hydrolyzes under acid catalysis to give two alcohol functionalities and a cyclopentanone. The ketal polymer is insoluble in an aqueous developer, while the hydrolyzed products are soluble. The decomposition temperature in the presence of acid was below room temperature. The polymer has high transparency in the deep UV region and its absorbances were 0.015 μm-1 at 248 nm and 0.163 μm-1 at 193 nm. The existence of the generated cyclopentanone after deprotection improves sensitivity by increasing acid diffusion.
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DOI
10.1016/S0032-3861(99)00154-8
ISSN
0032-3861
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ECHE_Journal Papers
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