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Choi, Nam-Soon
Energy Materials Lab
Research Interests
  • Rechargeable lithium battery, electrolytes for next generation Mg and Na battery

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Effect of Electrolytes on Electrochemical Properties of Magnesium Electrodes

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Title
Effect of Electrolytes on Electrochemical Properties of Magnesium Electrodes
Author
Ha, Se-YoungRyu, AnnaCho, WoosukWoo, Sang-GilKim, Jae-HunLee, Kyu TaeKim, Jeom-SooChoi, Nam-Soon
Issue Date
2012-12
Publisher
KOREAN ELECTROCHEMISTRY SOC
Citation
JOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY, v.3, no.4, pp.159 - 164
Abstract
Magnesium (Mg) deposition and dissolution behaviors of 0.2 M $MgBu_2-(AlCl_2Et)_2$, 0.5 M $Mg(ClO_4)_2$, and 0.4M $(PhMgCl)_2-AlCl_3$-based electrolytes with and without tris(pentafluorophenyl) borane (TPFPB) are investigated by ex situ scanning electron microscopy (SEM) and galvanostatic cycling of Mg/copper (Cu) cells. To ascertain the factors responsible for the anodic stability of the electrolytes, linear sweep voltammogrametry (LSV) experiments for various electrolytes and solvents are conducted. The effects of TPFPB as an additive on the anodic stability of 0.4M ($(PhMgCl)_2-AlCl_3$/THF electrolyte are also discussed.
URI
https://scholarworks.unist.ac.kr/handle/201301/6645
DOI
10.5229/JECST.2012.3.4.159
ISSN
2093-8551
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ECHE_Journal Papers
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