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- Yoo, Changho
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Immobilization of a trimeric ruthenium cluster in mesoporous chromium terephthalate and its catalytic application
- Author(s)
- Sivan, Sanil E., Oh, Kyung-Ryul, Yoon, Ji-Woong, Yoo, Changho, Hwang, Young Kyu
- Issued Date
- 2022-09
- Citation
- DALTON TRANSACTIONS, v.51, no.35, pp.13189 - 13194
- Abstract
- Molecular trimeric ruthenium carboxylate clusters (Ru-3 clusters) have been introduced into the pore channels of mesoporous metal-organic framework chromium terephthalate [MIL-101(Cr)] by employing a facile two-step post-synthetic strategy in which diamine hooks anchored on the framework metal nodes of the MOF are used to covalently immobilize the Ru-3 clusters. The catalytic activity of the isolated Ru-3 clusters in the pore channels of the MOF was significantly improved compared to the bulk counterpart.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1477-9226
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