Full metadata record
DC Field | Value | Language |
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dc.citation.number | 33 | - |
dc.citation.startPage | 2302086 | - |
dc.citation.title | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.volume | 33 | - |
dc.contributor.author | Kim, Junhee | - |
dc.contributor.author | Choi, Soonyoung | - |
dc.contributor.author | Baek, Jinsu | - |
dc.contributor.author | Park, Yong Il | - |
dc.contributor.author | Kim, Jin Chul | - |
dc.contributor.author | Jeong, Ji‐Eun | - |
dc.contributor.author | Jung, Hyocheol | - |
dc.contributor.author | Kwon, Tae-Hyuk | - |
dc.contributor.author | Kim, Byeong‐Su | - |
dc.contributor.author | Lee, Sang‐Ho | - |
dc.date.accessioned | 2023-12-21T12:39:27Z | - |
dc.date.available | 2023-12-21T12:39:27Z | - |
dc.date.created | 2023-06-07 | - |
dc.date.issued | 2023-08 | - |
dc.description.abstract | Topology control of polymers is critical for determining their physical properties and potential applications; in particular, topologies that incorporate numerous hydrogen bonding (H-bonding) donors and acceptors along the polymer chains considerably influence the formation of different inter- and intramolecular H-bonding motifs. In this study, the high-level control of inter- and intramolecular H-bonding is investigated in topology-controlled poly(glycidoxy carbonyl benzoic acid)s (PGCs). Three types of topology-controlled PGCs (i.e., linear, hyperbranched, and branched cyclic structures having a similar degree of polymerization) are prepared by introducing aromatic carboxylic acids into the corresponding polyglycidols (PGs) via quantitative post-polymerization modification with phthalic anhydride. The obtained three types of PGCs demonstrated the high-level interplay between the inter- and intramolecular H-bonding in polymer chains by exhibiting the pH-dependent self-association properties in the solution state and the strong adhesion properties in the bulk state with high transparency. Interestingly, the dramatically enhanced adhesive property by 2.6-fold is demonstrated by simple mixing of branched cyclic PGC and topology-controlled PGs to promote the cooperative H-bonding between polymer chains. The new class of cooperative H-bonding is anticipated between topology-controlled polymers to contribute to the development of advanced adhesive and the high potential in biological and biomedical applications due to its excellent biocompatibility. | - |
dc.identifier.bibliographicCitation | ADVANCED FUNCTIONAL MATERIALS, v.33, no.33, pp.2302086 | - |
dc.identifier.doi | 10.1002/adfm.202302086 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.scopusid | 2-s2.0-85158024908 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/64406 | - |
dc.identifier.wosid | 000980977200001 | - |
dc.language | 영어 | - |
dc.publisher | Wiley | - |
dc.title | Design of Topology‐Controlled Polyethers toward Robust Cooperative Hydrogen Bonding | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary;Chemistry, Physical;Nanoscience & Nanotechnology;Materials Science, Multidisciplinary;Physics, Applied;Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry;Science & Technology - Other Topics;Materials Science;Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | cooperative H-bonding | - |
dc.subject.keywordAuthor | poly(glycidoxy carbonyl benzoic acid) | - |
dc.subject.keywordAuthor | polyethers | - |
dc.subject.keywordAuthor | polymer adhesives | - |
dc.subject.keywordAuthor | polymer topology control | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | DBU | - |
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