The nonradiative decay of the allyl radical excited B 2A1 state studied by picosecond time-resolved photoelectron spectroscopy
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- The nonradiative decay of the allyl radical excited B 2A1 state studied by picosecond time-resolved photoelectron spectroscopy
- Schultz, Thomas; Fischer, I
- RESONANT MULTIPHOTON IONIZATION; ULTRAFAST INTERNAL-CONVERSION; KINETIC-ENERGY PHOTOELECTRON; ELECTRONIC-SPECTRUM; RYDBERG STATES; SUPERSONIC JET; ORIGIN BAND; DYNAMICS; PHOTOIONIZATION; RELAXATION
- Issue Date
- AMER INST PHYSICS
- JOURNAL OF CHEMICAL PHYSICS, v.107, no.19, pp.8197 - 8200
- The nonradiative decay rates of the vibrational ground state and the v7 fundamental in the electronically excited B 2A1 state of the allyl radical, C3H5, are studied by picosecond time-resolved pump-probe photoelectron spectroscopy. The states decay by internal conversion with a time constant of 20 and 16 ps, respectively.
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