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Untangling pi-pi*/n-pi* orbital interactions via time-resolved photoelectron spectroscopy

Author(s)
Shaffer, JPSchultz, ThomasSchmitt, MUnderwood, JGStolow, A
Issued Date
2001
URI
https://scholarworks.unist.ac.kr/handle/201301/6293
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0035776686
Citation
SPRINGER SERIES IN CHEMICAL PHYSICS, v.66, pp.338 - 340
Abstract
The ultrafast photochemical dynamics of π-π*/n-π* orbital interactions are determined using time-resolved photoelectron spectroscopy. We compare the spectra of several linear α,β-enones and 1,3-butadiene. We find two different ultrafast decay paths for the α,β-enones, both predicted by ab initio calculations.
Publisher
Springer Verlag
ISSN
0172-6218

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