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- Schultz, Thomas
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Dynamics of excited-state proton transfer systems via time-resolved photoelectron spectroscopy
- Author(s)
- Lochbrunner, S, Schultz, Thomas, Schmitt, M, Shaffer, JP, Zgierski, MZ, Stolow, A
- Issued Date
- 2001-02
- Citation
- JOURNAL OF CHEMICAL PHYSICS, v.114, no.6, pp.2519 - 2522
- Abstract
- The use of time-resolved photoelectron spectroscopy for analyzing excited state intramolecular proton transfer (ESIPT) and internal conversion dynamics in a model system was investigated. The photoelectron spectra of both the excited state enol and keto tautomers were presented as a function of pump laser wavelength and pump-probe time delay. It was found that the internal conversion dynamics in o-hydroxybenzaldehyde (OHBA) was influenced by interactions with a close-lying nπ* state.
- Publisher
- AMER INST PHYSICS
- ISSN
- 0021-9606
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