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Lee, Sang-Young
Energy Soft-Materials Lab.
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Potential application of microporous structured poly(vinylidene fluoride-hexafluoropropylene)/poly(ethylene terephthalate) composite nonwoven separators to high-voltage and high-power lithium-ion batteries

Author(s)
Jeong, Hyun-SeokChoi, Eun-SunKim, Jong HunLee, Sang-Young
Issued Date
2011-05
DOI
10.1016/j.electacta.2011.03.040
URI
https://scholarworks.unist.ac.kr/handle/201301/6154
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79956352146
Citation
ELECTROCHIMICA ACTA, v.56, no.14, pp.5201 - 5204
Abstract
We demonstrate potential application of a new composite non-woven separator, which is comprised of a phase inversion-controlled, microporous polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP) gel polymer electrolyte and a polyethylene terephthalate (PET) non-woven support, to high-voltage and high-power lithium-ion batteries. In comparison to a commercialized polyethylene (PE) separator, the composite non-woven separator exhibits distinct improvements in microporous structure and liquid electrolyte wettability. Based on the understanding of the composite non-woven separator, cell performances of the separator at challenging charge/discharge conditions are investigated and discussed in terms of ion transport of the separator and AC impedance of the cell. The aforementioned advantageous features of the composite non-woven separator play a key role in providing facile ion transport and suppressing growth of cell impedance during cycling, which in turn contribute to superior cell performances at harsh charge/discharge conditions such as high voltages and high current densities.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
ISSN
0013-4686

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