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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

Author(s)
Son, SUPark, KHLee, YSKim, BYChoi, CHLah, Myoung SooJang, YHJang, DJChung, YK
Issued Date
2004-11
DOI
10.1021/ic049514f
URI
https://scholarworks.unist.ac.kr/handle/201301/6075
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=7244256018
Citation
INORGANIC CHEMISTRY, v.43, no.22, pp.6896 - 6898
Abstract
Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)(3)(2+) and Ru(terpy)(2)(2+), respectively, were synthesized. The complex, which is analogous to Ru(terpy)(2)(2+), exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.
Publisher
AMER CHEMICAL SOC
ISSN
0020-1669

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