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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Novel 36-membered dodecanuclear manganese metalladiazamacrocycle

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Title
Novel 36-membered dodecanuclear manganese metalladiazamacrocycle
Author
John, RPLee, KLah, Myoung Soo
Issue Date
2004
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, no.23, pp.2660 - 2661
Abstract
A novel dodecanuclear manganese metalladiazamacrocycle was synthesized employing a new pentadentate ligand N-2-pentenoylsalicylhydrazide (H 3tpeshz) by supramolecular self-assembly. The backbone of this metal-organic assembly is a repeating unit of an M-N-N-M linkage that extends to complete a 36-membered cyclic structure involving 12 manganese(III) centers. Successive manganese centers are in a chemically different ⋯ ABABAB⋯-type environment while the chirality varies as ⋯ΛΛΔΔΛΛ⋯. The unique arrangement of manganese centers results in a highly puckered metalladiazamacrocycle with an S6-point group symmetry.
URI
https://scholarworks.unist.ac.kr/handle/201301/5999
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=11144273350
DOI
10.1039/b407668k
ISSN
1359-7345
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CHM_Journal Papers
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