BROWSE

Related Researcher

Author's Photo

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

ITEM VIEW & DOWNLOAD

Solvent effect on the nature of the metallamacrocycles formed: Formation of octanuclear and dodecanuclear manganese metalladiazamacrocycles

Cited 2 times inthomson ciCited 2 times inthomson ci
Title
Solvent effect on the nature of the metallamacrocycles formed: Formation of octanuclear and dodecanuclear manganese metalladiazamacrocycles
Author
John, Rohith P.Lee, KyungjinLee, KyungjaePark, MiraLah, Myoung Soo
Issue Date
2007-11
Publisher
KOREAN CHEMICAL SOC
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.28, no.11, pp.2009 - 2014
Abstract
Depending on the choice of coordinating solvent molecules, the size and nuclearity of metallamacrocycles formed could be controlled. When a manganese ion was assembled with a pentadentate ligand, N-trans-(pentenoyl) salicylhydrazide in amide solvents such as dimethylformamide (DMF) or dimethylacetamide (DMA), an S6 symmetry puckered dodecanuclear metalladiazamacrocycle with a ⋯(ΛΛΔΔ) (ΛΛΔΔ)⋯ chiral sequence was obtained. However, in an alcoholic solvent such as methanol or ethanol while keeping the other conditions the same, an S8 symmetry octanuclear metalladiazamacrocycle with a ⋯(ΛΔ)(ΛΔ)⋯ chiral sequence was obtained.
URI
https://scholarworks.unist.ac.kr/handle/201301/5941
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=36949031428
ISSN
0253-2964
Appears in Collections:
CHM_Journal Papers
Files in This Item:
There are no files associated with this item.

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qrcode

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU