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Suh, Yung Doug
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TEMPERATURE-DEPENDENT RAMAN-STUDY ON C-70 FILM - OBSERVATION OF A ROTATIONAL ORDERING TRANSITION

Author(s)
Shin, Eun-jooSong, Ok-KeunKim, DonghoSuh, Yung DougYang, Sung IkKim, Seong Keun
Issued Date
1994-02
DOI
10.1016/0009-2614(93)E1452-M
URI
https://scholarworks.unist.ac.kr/handle/201301/58802
Citation
CHEMICAL PHYSICS LETTERS, v.218, no.1-2, pp.107 - 114
Abstract
An orientational ordering transition was observed near 260 K from a C-70 film in a temperature-dependent Raman study. The 1183 cm(-1) Raman band shows a rather dramatic change in both frequency and bandwidth over the range of 220-280 K. The low-frequency Raman band at 260 cm(-1) disappears, and at its expense, a new band emerges at 266 cm(-1) as the temperature is decreased. The relatively smooth transition in temperature is attributed to the stacking disorder in molecular packing and the nonuniform orientational conformation of C-70 solid.
Publisher
ELSEVIER SCIENCE BV
ISSN
0009-2614
Keyword
TRANSMISSION ELECTRON-DIFFRACTIONSINGLE-CRYSTAL C-60SOLID C-60VIBRATIONAL FREQUENCIESPRESSURE-DEPENDENCEMOLECULAR-DYNAMICSPHASE-TRANSITIONINFRARED-SPECTRACARBON CLUSTERSC60

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