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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Assembly of a heterobinuclear 2-D network: A rare example of endo- and exocyclic coordination of Pd-II/Ag-I in a single macrocycle

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Title
Assembly of a heterobinuclear 2-D network: A rare example of endo- and exocyclic coordination of Pd-II/Ag-I in a single macrocycle
Author
Yoon, ISeo, JLee, JEPark, KMKim, JSLah, Myoung SooLee, SS
Issue Date
2006-05
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.45, no.9, pp.3487 - 3489
Abstract
The S3O2 macrocycle L-1 was synthesized by a dithiol-dihalide coupling reaction under high-dilution conditions. The reaction of L-1 with K2PdCl4 afforded an exocoordinated complex 1, [cisCl(2)Pd(L-1)], which can then be manipulated to provide a heterobinuclear complex 3, J[Pd(L-1)Ag(NO3)(2.5)](NO3)(0.5)}(n), utilizing endocyclic Pd-II and exocyclic Ag-I in a single macrocycle through a successive reaction with AgNO3. The network of 3 contains a unique honeycomb-like 2-D sheet made up of the repeating unit [Ag-6(NO3)(6)].
URI
https://scholarworks.unist.ac.kr/handle/201301/5880
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33646458365
DOI
10.1021/ic060005i
ISSN
0020-1669
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CHM_Journal Papers
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