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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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Triangular assembly through charged hydrogen bonds in polar solvent

Author(s)
Lee, Ho YongMoon, DohyunLah, Myoung SooHong, Jong-In
Issued Date
2006-11
DOI
10.1021/jo061543f
URI
https://scholarworks.unist.ac.kr/handle/201301/5878
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33751563150
Citation
JOURNAL OF ORGANIC CHEMISTRY, v.71, no.24, pp.9225 - 9228
Abstract
(Chemical Equation Presented) We have demonstrated a triangular assembly driven by 12 charged hydrogen bonds and π-π interactions. This assembly is stable even in polar solvents because of its charged hydrogen-bond nature. Helical arrangement of the complex is confirmed by its crystal structure. A solution structure is assigned to the D3 isomer corresponding to the solid-state structure by temperature-dependent 1H NMR experiments.
Publisher
AMER CHEMICAL SOC
ISSN
0022-3263
Keyword
MOLECULAR BOXESNONCOVALENT SYNTHESISGUEST MOLECULESCAPSULEWATERENCAPSULATIONCOMPLEXATIONDIMERIZATIONRECOGNITIONCHIRALITY

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