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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Metalladiazamacrocycles: Metallamacrocycles as potential supramolecular host system for small organic guest molecules and supramolecular building blocks for metal organic frameworks

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Title
Metalladiazamacrocycles: Metallamacrocycles as potential supramolecular host system for small organic guest molecules and supramolecular building blocks for metal organic frameworks
Author
John, Rohith P.Moon, DohyunLah, Myoung Soo
Issue Date
2007-06
Publisher
TAYLOR & FRANCIS LTD
Citation
SUPRAMOLECULAR CHEMISTRY, v.19, no.4-5, pp.295 - 308
Abstract
Metalladiazamacrocycles, coordination driven potential supramolecular host systems, can be obtained via cyclic linkages of the metal ions and the bridging ligands, N-acylsalicylhydrazides. The nuclearity and the shape of the metallamacrocycles could be modulated by controlling the steric interactions caused by N-acyl tails of the ligands. The macrocycles could be utilized for recognition of small organic guest molecules using their hydrophobicity/hydrophilicity, the size and shape/symmetry of the cavities. In addition, these macrocycles can be used as the supramolecular building blocks for the construction of systematically tuned metal-organic frameworks since these clusters have several replaceable solvent sites which could serve as connecting nodes for the formaton of network structures.
URI
https://scholarworks.unist.ac.kr/handle/201301/5874
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=34547942467
DOI
10.1080/10610270701275083
ISSN
1061-0278
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CHM_Journal Papers
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