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- Lah, Myoung Soo
- Frontier Energy Storage Material Lab.
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A chiral pentadecanuclear metallamacrocycle with a sextuple twisted Mobius topology
- Author(s)
- John, Rohith P., Park, Mira, Moon, Dohyun, Lee, Kyungjin, Hong, Seunghee, Zou, Yang, Hong, Chang Seop, Lah, Myoung Soo
- Issued Date
- 2007-11
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.129, no.46, pp.14142 - +
- Abstract
- A C (3) symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N -phenylpropiolyl salicylhydrazide (H(3)L), and a manganese ion. The combination of a narrow C alpha-C beta region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Mobius topology was stabilized by extensive weak intramolecular interactions.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0002-7863
- Keyword
- CHEMISTRY, METALLADIAZAMACROCYCLE, NUCLEARITY, MOLECULES, CRYSTALS
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