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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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A chiral pentadecanuclear metallamacrocycle with a sextuple twisted Mobius topology

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Title
A chiral pentadecanuclear metallamacrocycle with a sextuple twisted Mobius topology
Author
John, Rohith P.Park, MiraMoon, DohyunLee, KyungjinHong, SeungheeZou, YangHong, Chang SeopLah, Myoung Soo
Issue Date
2007-11
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.129, no.46, pp.14142 - +
Abstract
A C (3) symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N -phenylpropiolyl salicylhydrazide (H(3)L), and a manganese ion. The combination of a narrow C alpha-C beta region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Mobius topology was stabilized by extensive weak intramolecular interactions.
URI
https://scholarworks.unist.ac.kr/handle/201301/5868
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=36448937498
DOI
10.1021/ja075945w
ISSN
0002-7863
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CHM_Journal Papers
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