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- Moon, Hoi Ri
- Functional Inorganic Nanomaterials Lab for Energy
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Post-synthetic ligand cyclization in metal-organic frameworks through functional group connection with regioisomerism
- Author(s)
- Kim, Dasom, Yoo, Haneul, Kim, Kyunghwan, Kim, Dongwook, Kim, Ki Tae, Kim, Cheoljae, Kim, Jin Yeong, Moon, Hoi Ri, Kim, Min
- Issued Date
- 2022-05
- Citation
- CHEMICAL COMMUNICATIONS, v.58, no.40, pp.5948 - 5951
- Abstract
- A covalent connection between two orthogonal functional groups (-NH2 and -OH) in metal-organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66-2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66-2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
- Keyword
- TRIFLUOROMETHYL GROUPS, FLEXIBILITY, UIO-66, CO2
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