File Download
There are no files associated with this item.
SFX Link
- Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
- Lah, Myoung Soo
- Frontier Energy Storage Material Lab.
Views & Downloads
Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
2D Layered metal-organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks
- Author(s)
- Moon, Dohyun, Song, Jiheh, Lah, Myoung Soo
- Issued Date
- 2009
- DOI
- 10.1039/b813603c
- Citation
- CRYSTENGCOMM, v.11, no.5, pp.770 - 776
- Abstract
- Two different 2D layered metal-organic frameworks (MOFs) have been prepared using a hexanuclear manganese metallamacrocycle and an octanuclear manganese metallamacrocycle as supramolecular building blocks via a simple change of the solvent used and/or addition of a templating agent. While the sheets in the 2D MOF [Mn(6)(pshz)(6)(bpea)(2)(dma)(2)](n), 2 (where, pshz(3-) is N-propionylsalicylhydrazidate, bpea is 1,2-bis(pyridyl)ethane, and dma is N,N-dimethylacetamide), built based on a hexanuclear metalladiazamacrocycle are in a staggered orientation, the sheets in the 2D MOF [Mn(8)(pshz)(8)(bpea)(2)(dma)(4)](n), 3, built based on an octanuclear metalladiazamacrocycle are in an eclipsed orientation. However, both MOFs have the same 3-connected 4.8(2) network topology.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1466-8033
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.