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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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2D Layered metal-organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks

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Title
2D Layered metal-organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks
Author
Moon, DohyunSong, JihehLah, Myoung Soo
Issue Date
2009
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.11, no.5, pp.770 - 776
Abstract
Two different 2D layered metal-organic frameworks (MOFs) have been prepared using a hexanuclear manganese metallamacrocycle and an octanuclear manganese metallamacrocycle as supramolecular building blocks via a simple change of the solvent used and/or addition of a templating agent. While the sheets in the 2D MOF [Mn(6)(pshz)(6)(bpea)(2)(dma)(2)](n), 2 (where, pshz(3-) is N-propionylsalicylhydrazidate, bpea is 1,2-bis(pyridyl)ethane, and dma is N,N-dimethylacetamide), built based on a hexanuclear metalladiazamacrocycle are in a staggered orientation, the sheets in the 2D MOF [Mn(8)(pshz)(8)(bpea)(2)(dma)(4)](n), 3, built based on an octanuclear metalladiazamacrocycle are in an eclipsed orientation. However, both MOFs have the same 3-connected 4.8(2) network topology.
URI
https://scholarworks.unist.ac.kr/handle/201301/5806
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=65349150047
DOI
10.1039/b813603c
ISSN
1466-8033
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CHM_Journal Papers
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