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- Lah, Myoung Soo
- Frontier Energy Storage Material Lab.
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Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
- Author(s)
- Chun, Jiseul, Jung, Il Gu, Kim, Hae Jin, Park, Mira, Lah, Myoung Soo, Son, Seung Uk
- Issued Date
- 2009-07
- Citation
- INORGANIC CHEMISTRY, v.48, no.14, pp.6353 - 6355
- Abstract
- A new building block containing an imidazolium salt was synthesized and used for the construction of supramolecular networks with metal ions. We discovered the concomitant formation of the N-heterocyclic carbene-copper complex (CN = 2) in the selfassembly of imidazolium dlcarboxylates and copper nitrates in N, N-dimethylformamide under heating. The proton in the 2 position of the imidazolium salt was abstracted, and CuII was reduced to CuI during the self-assembly process.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0020-1669
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