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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions

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Title
Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
Author
Chun, JiseulJung, Il GuKim, Hae JinPark, MiraLah, Myoung SooSon, Seung Uk
Issue Date
2009-07
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.48, no.14, pp.6353 - 6355
Abstract
A new building block containing an imidazolium salt was synthesized and used for the construction of supramolecular networks with metal ions. We discovered the concomitant formation of the N-heterocyclic carbene-copper complex (CN = 2) in the selfassembly of imidazolium dlcarboxylates and copper nitrates in N, N-dimethylformamide under heating. The proton in the 2 position of the imidazolium salt was abstracted, and CuII was reduced to CuI during the self-assembly process.
URI
https://scholarworks.unist.ac.kr/handle/201301/5798
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=67650458482
DOI
10.1021/ic900846s
ISSN
0020-1669
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CHM_Journal Papers
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