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- Oh, Hyunchul
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Quantum cryo-sieving for hydrogen isotope separation in microporous frameworks: an experimental study on the correlation between effective quantum sieving and pore size
- Author(s)
- Oh, Hyunchul, Park, Kyo Sung, Kalidindi, Suresh Babu, Fischer, Roland A., Hirscher, Michael
- Issued Date
- 2013-01
- Citation
- JOURNAL OF MATERIALS CHEMISTRY A, v.1, no.10, pp.3189 - 3504
- Abstract
- Different microporous frameworks have been experimentally investigated by cryogenic (below 77 K) hydrogen and deuterium adsorption measurements. The D-2/H-2 molar ratio is strongly dependent on pore size, pressure and temperature. The experiments clearly indicate that the optimum pore diameter for quantum sieving lies between 3.0 angstrom and 3.4 angstrom.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 2050-7488
- Keyword
- MONTE-CARLO SIMULATIONS, METAL-ORGANIC FRAMEWORK, ADSORPTION, H-2, D-2
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