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- Oh, Hyunchul
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MFU-4 - A Metal-Organic Framework for Highly Effective H-2/D-2 Separation
- Author(s)
- Teufel, Julia, Oh, Hyunchul, Hirscher, Michael, Wahiduzzaman, Mohammad, Zhechkov, Lyuben, Kuc, Agnieszka, Heine, Thomas, Denysenko, Dmytro, Volkmer, Dirk
- Issued Date
- 2013-01
- Citation
- ADVANCED MATERIALS, v.25, no.4, pp.635 - 639
- Abstract
- The metal-organic framework, MFU-4, possessing small cavities and apertures, is exploited for quantum sieving of hydrogen isotopes. Quantum mechanically, a molecule confined in a small cavity shows an increase in effective size depending on the particle mass, which leads to a faster deuterium adsorption from a H-2/D-2 isotope mixture.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 0935-9648
- Keyword (Author)
- hydrogen isotopes, gas adsorption, quantum sieving, isotope separation, metal-organic frameworks
- Keyword
- HYDROGEN ISOTOPES, AB-INITIO, ADSORPTION, H-2, ADSORBENTS, CARBON
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