The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
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- The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
- Braymer, Joseph J.; O'Neill, Kevin P.; Rohde, Jan-Uwe; Lim, Mi Hee
- Issue Date
- WILEY-V C H VERLAG GMBH
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.51, no.22, pp.5376 - 5380
- An Fe IV=O group meets with H 2O 2! Reaction of high-valent iron with the reactive oxygen species (ROS) hydrogen peroxide (H 2O 2) is in general reserved for heme centers. Employing a biomimetic metal complex, the direct reaction of a mononuclear nonheme oxoiron(IV) species with H 2O 2 was observed and studied mechanistically, offering a new perspective for the chemistry between ROS and high-valent oxometal complexes
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