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The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide

Author(s)
Braymer, Joseph J.O'Neill, Kevin P.Rohde, Jan-UweLim, Mi Hee
Issued Date
2012-05
DOI
10.1002/anie.201200901
URI
https://scholarworks.unist.ac.kr/handle/201301/5728
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84861501411
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.51, no.22, pp.5376 - 5380
Abstract
An Fe IV=O group meets with H 2O 2! Reaction of high-valent iron with the reactive oxygen species (ROS) hydrogen peroxide (H 2O 2) is in general reserved for heme centers. Employing a biomimetic metal complex, the direct reaction of a mononuclear nonheme oxoiron(IV) species with H 2O 2 was observed and studied mechanistically, offering a new perspective for the chemistry between ROS and high-valent oxometal complexes
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1433-7851
Keyword (Author)
bioinorganic chemistryenzyme modelsironreaction mechanismsreactive oxygen species
Keyword
CYCLOOCTENE EPOXIDATIONATOM TRANSFERMYCOBACTERIUM-TUBERCULOSISCHEMICAL-PROPERTIESOXYGEN ACTIVATIONCATALASE ACTIVITYCRYSTAL-STRUCTUREIRON ENZYMESFERRYL IONCOMPLEXES

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