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Related Researcher
- Rohde, Jan-Uwe
- Transition Metal Chemistry
-
Research Interests
- Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.
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The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
- Title
- The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
- Keywords
- bioinorganic chemistry; enzyme models; iron; reaction mechanisms; reactive oxygen species
- Issue Date
- 2012-05
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.51, no.22, pp.5376 - 5380
- Abstract
- An Fe IV=O group meets with H 2O 2! Reaction of high-valent iron with the reactive oxygen species (ROS) hydrogen peroxide (H 2O 2) is in general reserved for heme centers. Employing a biomimetic metal complex, the direct reaction of a mononuclear nonheme oxoiron(IV) species with H 2O 2 was observed and studied mechanistically, offering a new perspective for the chemistry between ROS and high-valent oxometal complexes
- URI
- ; Go to Link
- ISSN
- 1433-7851
- Appears in Collections:
- PHY_Journal Papers
- Files in This Item:
- 000304345800018.pdf Download
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