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- Rohde, Jan-Uwe
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Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2
- Author(s)
- Kelley, Matthew R., Rohde, Jan-Uwe
- Issued Date
- 2012-03
- Citation
- CHEMICAL COMMUNICATIONS, v.48, no.23, pp.2876 - 2878
- Abstract
- An (alkene)peroxoiridium(iii) complex, [Ir(L)(cod)(O 2)] [where LH = PhNC(NMe 2)NHPh and cod = 1,5-cyclooctadiene], was identified as an intermediate in the reaction of the Ir I precursor [Ir(L)(cod)] with O 2 and characterized by spectroscopic methods. Decay of the intermediate and further reaction with 1,5-cyclooctadiene produced 4-cycloocten-1-one
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
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