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Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

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Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2

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Title
Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2
Author
Kelley, Matthew R.Rohde, Jan-Uwe
Issue Date
2012-03
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.48, no.23, pp.2876 - 2878
Abstract
An (alkene)peroxoiridium(iii) complex, [Ir(L)(cod)(O 2)] [where LH = PhNC(NMe 2)NHPh and cod = 1,5-cyclooctadiene], was identified as an intermediate in the reaction of the Ir I precursor [Ir(L)(cod)] with O 2 and characterized by spectroscopic methods. Decay of the intermediate and further reaction with 1,5-cyclooctadiene produced 4-cycloocten-1-one
URI
https://scholarworks.unist.ac.kr/handle/201301/5721
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84857219382
DOI
10.1039/c2cc17332h
ISSN
1359-7345
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CHM_Journal Papers
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