A BENT MIXED-VALENCE MANGANESE(III/II/III) COMPLEX - A NEW CLASS OF TRINUCLEAR, ACETATE BRIDGED SCHIFFS BASE COMPOUNDS EXHIBITING A G = 2 MULTILINE ESR SIGNAL
JOURNAL OF THE CHEMICAL SOCIETY - SERIES CHEMICAL COMMUNICATIONS, no.2, pp.84 - 86
Abstract
The e.s.r. spectrum of the bent mixed valence Mn(III/II/III) (saladhp) 2(OAc)4(MeOH)2[saladhp = 2-(salicylideneaminato)- 1,3-dihydroxy-2-methylpropane] in dimethylformamide provides the observation of a multiline e.s.r. signal from a trinuclear mixed-valence manganese complex and allows for the comparison of magnetic and spectroscopic properties of related models for the photosynthetic water oxidizing enzyme