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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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THE TETRANUCLEAR CLUSTER FEIII[FEIII(SALICYLHYDROXIMATO)(MEOH)(ACETATE)]3 IS AN ANALOG OF M3+(9-CROWN-3)

Author(s)
Lah, Myoung SooKIRK, MLHATFIELD, WPECORARO, VL
Issued Date
1989-11
DOI
10.1039/c39890001606
URI
https://scholarworks.unist.ac.kr/handle/201301/5623
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=37049084045
Citation
JOURNAL OF THE CHEMICAL SOCIETY - SERIES CHEMICAL COMMUNICATIONS, no.21, pp.1606 - 1608
Abstract
The first example of transition metal co-ordination to ethereal like oxygens of a 9-metallocrown-3 ether is seen in FeIII[Fe III(salicylhydroximato)(MeOH)(acetate)]3 and leads to an unusual tetranuclear cluster which exhibits both inter- and intra-cluster antiferromagnetic interactions and an S = 5 ground state.
Publisher
Royal Society of Chemistry
ISSN
0022-4936

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