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- Lah, Myoung Soo
- Frontier Energy Storage Material Lab.
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Transformation of a Cluster-Based Metal-Organic Framework to a Rod Metal-Organic Framework
- Author(s)
- Won, Somi, Jeong, Seok, Kim, Dongwook, Seong, Junmo, Lim, Jaewoong, Moon, Dohyun, Baek, Seung Bin, Lah, Myoung Soo
- Issued Date
- 2022-01
- Citation
- CHEMISTRY OF MATERIALS, v.34, no.1, pp.273 - 278
- Abstract
- A highly stable and rigid rod metal-organic framework (MOF) is obtained by the single-crystal-to-single-crystal transformation of a Zr-6 cluster-based MOF with highly interconnected but geometrically mismatched building blocks. The transformation results in a significant framework contraction, which comes from the formation of infinite chains of carboxylate- and aquo-linked Zr-6 clusters as a one-dimensional rod secondary building unit. The permanently microporous rod MOF is stable in a variety of solvents, including H2O, and even under very harsh conditions, such as strongly acidic and basic aqueous solutions at 100 degrees C.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0897-4756
- Keyword
- RETICULAR CHEMISTRY
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