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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Novel 48-membered hexadecanuclear and 60-membered icosanuclear manganese metallamacrocycles

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Title
Novel 48-membered hexadecanuclear and 60-membered icosanuclear manganese metallamacrocycles
Author
Liu, WenlongLee, KyungjinPark, MiraJohn, Rohith P.Moon, DohyunZou, YangLiu, XinfangRi, Hyeong-CheolKim, Ghyung HwaLah, Myoung Soo
Issue Date
2008-10
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.47, no.19, pp.8807 - 8812
Abstract
Either an S-8 symmetrical 48-membered hexadecanuclear or an S-10 symmetrical 60-membered icosanuclear manganese metallamacrocycle was self-assembled using a manganese ion and a ditopic pentadentate ligand. This was either N-4-phenylbenzoylsalicylhydrazide (H(3)pbshz) containing a rigid rod-shaped, bulky biphenyl residue as a terminal N-acyl group or N-3,3-diphenylpropionylsalicylhydrazide (H(3)dppshz) containing a flexible beta-branched N-acyl group, but with two sterically bulky phenyl residues at the C beta position. The backbone of these metal-organic assemblies is a repeating unit consisting of a -[Mn-N-N-] link that extends to complete either the 48-membered cyclic structure involving 16 manganese(III) centers and 16 ditopic linker ligands or the 60-membered cyclic structure involving 20 manganese(III) centers and 20 ditopic linker ligands (depending on the ligand used). Even though the nuclearity of the metallamacrocycles was different, the successive manganese centers were in the same chiral sequence, ...(Lambda Lambda Delta Delta)(Lambda Lambda Delta Delta)...
URI
https://scholarworks.unist.ac.kr/handle/201301/5573
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=54149094296
DOI
10.1021/ic800708z
ISSN
0020-1669
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