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SUSCEPTIBILITY DISCONTINUITY IN SINGLE-CRYSTAL C60

Author(s)
LUO, WLWANG, HRUOFF, RSCIOSLOWSKI, JPHELPS, S
Issued Date
1994-07
DOI
10.1103/PhysRevLett.73.186
URI
https://scholarworks.unist.ac.kr/handle/201301/54551
Fulltext
https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.73.186
Citation
PHYSICAL REVIEW LETTERS, v.73, no.1, pp.186 - 188
Abstract
Magnetization of a large single C60 crystal was measured as functions of applied field and temperature. At T = 260 K, a discontinuity in susceptibility was observed. The relative change in total moment is 1.2%, independent of applied field to within experimental accuracy. This discontinuity is attributed to the change in the intramolecular geometry at the orientational order-disorder transition. This is the first experimental demonstration that the cooperative phase transition affects the magnetic susceptibility of a single molecule.
Publisher
AMER PHYSICAL SOC
ISSN
0031-9007
Keyword
ORIENTATIONAL-ORDERING TRANSITIONCURRENT MAGNETIC-SUSCEPTIBILITYICOSAHEDRAL C-60SPECTROSCOPYBUCKMINSTERFULLERENE

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