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Direct observation of polymer sheathing in carbon nanotube-polycarbonate composites

Author(s)
Ding, WEitan, AFisher, FTChen, XDikin, DAAndrews, RBrinson, LCSchadler, LSRuoff, RS
Issued Date
2003-11
DOI
10.1021/nl0345973
URI
https://scholarworks.unist.ac.kr/handle/201301/54489
Fulltext
https://pubs.acs.org/doi/10.1021/nl0345973
Citation
NANO LETTERS, v.3, no.11, pp.1593 - 1597
Abstract
A series of observations of polymer sheathing in multiwalled carbon nanotube (MWCNT)-polycarbonate composites are presented. This sheathing was observed in images of the composite fracture surface and is consistent with diameter distributions of the as-received and embedded MWCNTs. A novel nanomanipulation experiment, where the sheathing balls up when contacted by an AFM tip, confirms this phenomenon. This sheathing layer is direct evidence of substantial MWCNT-polymer interaction and will influence the mechanical properties of MWCNT-polymer composites.
Publisher
AMER CHEMICAL SOC
ISSN
1530-6984
Keyword
TRANSMISSION ELECTRON-MICROSCOPYMECHANICAL-PROPERTIESLOAD-TRANSFERSTRENGTHFIBERDEFORMATIONINTERFACEFRACTUREMATRIX

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