Hierarchical Porous Carbon Electrodes with Sponge-Like Edge Structures for the Sensitive Electrochemical Detection of Heavy Metals

Abstract

This article presents the development of a highly sensitive electrochemical heavy metal sensor based on hierarchical porous carbon electrodes with sponge-like edge structures. Micrometer-scale hierarchical nanoporous carbon electrodes were fabricated at a wafer-scale using cost-effective batch microfabrication technologies, including the carbon microelectromechanical systems technology and oxygen plasma etching. The sponge-like hierarchical porous structure and sub-micrometer edges of the nanoporous carbon electrodes facilitate fast electron transfer rate and large active sites, leading to the efficient formation of dense heavy metal alloy particles of small sizes during the preconcentration step. This enhanced the peak current response during the square wave anodic stripping voltammetry, enabling the detection of Cd(II) and Pb(II) at concentrations as low as 0.41 and 0.7 mu g L-1, respectively, with high sensitivity per unit sensing area (Cd: 109.45 nA mu g(-1) L mm(-2), Pb: 100.37 nA mu g(-1) L mm(-2)).