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Cho, Jaephil
Nano Energy Storage Materials Lab (NESM)
Research Interests
  • Li-ion battery, metal-air battery, redox-flow battery, flexible battery .

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LiNi0.74Co0.26-xMgxO2 cathode material for a Li-ion cell

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Title
LiNi0.74Co0.26-xMgxO2 cathode material for a Li-ion cell
Author
Cho, Jaephil
Keywords
BATTERIES; LINI1-XCOXO2; PERFORMANCE; ENHANCEMENT; LICOO2
Issue Date
2000-10
Publisher
AMER CHEMICAL SOC
Citation
CHEMISTRY OF MATERIALS, v.12, no.10, pp.3089 - 3094
Abstract
The effects of a partial substitution of Co with Mg in LiNi0.74Co0.26-xMgxO2 material on its X-ray structure, electrochemical properties, and thermal stability in the charged (delithiated) state have been studied. Results showed that the lattice parameters a and c as well as the cia ratio increased as the x-value increased. The DSC exothermic peak of the charged electrode LiNi0.74Co0.26-xMgxO2 (when x = 0.04 or higher) was significantly smaller than that of LiNi0.74Co0.26O2, indicating that the Mg substitution improved its thermal stability. The improvements of both the electrochemical and thermal stability are possibly due to the reduced cation mixing and improvement of layer structure by the expansion of the c-axis.
URI
https://scholarworks.unist.ac.kr/handle/201301/5248
DOI
10.1021/cm0001531
ISSN
0897-4756
Appears in Collections:
ECHE_Journal Papers
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