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Kim, Kwang S.
Center for Superfunctional Materials (CSM)
Research Interests
  • Theoretical/experimental nanosciences, molecular electronics spectroscopy, energy materials

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Isoreticular MOFs based on a rhombic dodecahedral MOP as a tertiary building unit

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Title
Isoreticular MOFs based on a rhombic dodecahedral MOP as a tertiary building unit
Author
Kim, DongwookLiu, XinfangOh, MinhakSong, XiaokaiZou, YangSingh, DevendraKim, Kwang S.Lah, Myoung Soo
Issue Date
2014-07
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.16, no.28, pp.6391 - 6397
Abstract
The solvothermal reactions of a Zn(ii) ion with ligands containing two 1,3-benzene dicarboxylate residues linked via bent organic linkers with different flexibilities resulted in the isoreticular metal-organic frameworks (MOFs) PMOF-4 and PMOF-5 based on a rhombic dodecahedral metal-organic polyhedron (MOP) as a tertiary building unit (TBU). The rhombic dodecahedral MOP was built using six [Zn2(COO)4] clusters as a 4-c secondary building unit (SBU) and eight [Zn2(COO)3] clusters as a 3-c SBU. The network of the isoreticular MOFs based on the rhombic dodecahedral Zn-MOP is a 3,3,4-c net with a zjz topology, which is different from those of similar MOFs, PMOF-3 and PCN-12, based on a cuboctahedral Cu-MOP as a 24-c TBU. However, both 24-c TBUs in all MOFs were quadruply interlinked to six neighboring TBUs to form the same underlying pcu topology.
URI
https://scholarworks.unist.ac.kr/handle/201301/5241
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84903462992
DOI
10.1039/c4ce00017j
ISSN
1466-8033
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CHM_Journal Papers
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