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Cho, Jaephil
Nano Energy Storage Material Lab.
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A mesoporous/crystalline composite material containing tin phosphate for use as the anode in lithium-ion batteries

Author(s)
Kim, ESon, DKim, TGCho, JaephilPark, BRyu, KSChang, SH
Issued Date
2004-11
DOI
10.1002/anie.200454080
URI
https://scholarworks.unist.ac.kr/handle/201301/5068
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=9244221591
Citation
ANGEWANDTE CHEMIE, v.116, no.44, pp.6113 - 6116
Abstract
Packed to capacity: The incorporation of mesoporous structures as a buffer layer enhances the structural stability of tin phosphate and alleviates the volume expansion of the tin phosphate anode during Li alloying/dealloying (see TEM image). The mesoporous tin phosphate/Sn2P2O 7 composite anode shows a large initial capacity (721 mAhg -1) and excellent cyclability (587 mAhg-1 at the 30th cycle.
Publisher
John Wiley & Sons Ltd.
ISSN
0044-8249

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