A mesoporous/crystalline composite material containing tin phosphate for use as the anode in lithium-ion batteries
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- A mesoporous/crystalline composite material containing tin phosphate for use as the anode in lithium-ion batteries
- Kim, E; Son, D; Kim, TG; Cho, Jaephil; Park, B; Ryu, KS; Chang, SH
- battery materials; electrochemistry; lithium; mesoporous materials; tin
- Issue Date
- John Wiley & Sons Ltd.
- ANGEWANDTE CHEMIE, v.116, no.44, pp.6113 - 6116
- Packed to capacity: The incorporation of mesoporous structures as a buffer layer enhances the structural stability of tin phosphate and alleviates the volume expansion of the tin phosphate anode during Li alloying/dealloying (see TEM image). The mesoporous tin phosphate/Sn2P2O 7 composite anode shows a large initial capacity (721 mAhg -1) and excellent cyclability (587 mAhg-1 at the 30th cycle.
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