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- Bielawski, Christopher W.
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Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption
- Author(s)
- Matoga, Dariusz, Gil, Barbara, Nitek, Wojciech, Todd, Alexander D., Bielawski, Christopher W.
- Issued Date
- 2014-06
- Citation
- CRYSTENGCOMM, v.16, no.23, pp.4959 - 4962
- Abstract
- A 2D layered microporous isonicotinate-supported manganese(ii) metal-organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2versus N 2.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1466-8033
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