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- Cho, Jaeheung
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Synthesis and crystal structure of nickel(II) complexes with bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine
- Author(s)
- Cho, Jaeheung, Lee, Yong-Min, Kim, Sung Yeon, Nam, Wonwoo
- Issued Date
- 2010-01
- Citation
- POLYHEDRON, v.29, no.1, pp.446 - 450
- Abstract
- A series of nickel(II) complexes having the (Me-Tp)2PMA ligand ((Me-Tp)2PMA = bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine) with nitrates (1), chlorides (2), and perchlorates (3) as anions were synthesized and isolated. All these complexes were successfully characterized by physicochemical methods including X-ray crystallographic analysis. In complex 1, the ligand binds in a bidentate N2 fashion, whereas in the cases of 2 and 3 the ligand binds in the tridentate N2S form. The coordination geometry around the nickel(II) atoms in these complexes is distorted octahedral.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- ISSN
- 0277-5387
- Keyword (Author)
- Nickel complexes, Hemilabile ligands, N,S-donor ligands, X-ray crystal structures
- Keyword
- COORDINATION CHEMISTRY, SMALL MOLECULES, LIGANDS, BEHAVIOR, SITES
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