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Kim, Guntae
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Research Interests
  • Solid Oxide Fuel Cells (SOFCs)& SOE, PEMFC, metal-air batteries, Metal-CO2 system, Catalyst for DRM

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Structural, electrical and electrochemical characteristics of La0.1Sr0.9Co1-xNbxO3-delta as a cathode material for intermediate temperature solid oxide fuel cells

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Title
Structural, electrical and electrochemical characteristics of La0.1Sr0.9Co1-xNbxO3-delta as a cathode material for intermediate temperature solid oxide fuel cells
Author
Yoo, SeonyoungKim, JiyounSong, Seung YoonLee, Dong WooShin, JeeyoungOk, Kang MinKim, Guntae
Issue Date
2014-04
Publisher
ROYAL SOC CHEMISTRY
Citation
RSC ADVANCES, v.4, no.36, pp.18710 - 18717
Abstract
The perovskite-oxides, such as (La, Sr)CoO3, have received a large amount of attention in recent years as cathode materials for intermediate temperature-solid oxide fuel cells (IT-SOFCs). In this study, we have investigated the structural, electrical, and electrochemical properties of La0.1Sr0.9Co1-xNbxO 3-δ (x = 0, 0.1, 0.15, and 0.2) cathodes under IT-SOFC operating conditions. Nb doping significantly improves the structural stability and electrochemical performance of La0.1Sr0.9Co 1-xNbxO3-δ (LSCNbx) oxides compared to undoped La0.1Sr0.9CoO3-δ (LSC). At a given temperature, the electrical conductivity decreases with further increases of the Nb doping content. The electrochemical performance of LSCNbx-GDC cathodes is measured using an LSCNbx-GDC/GDC/ Ni-GDC anode supported cell. For LSCNbx (x = 0.1), the maximum power density of a single cell is 1.478 W cm-2 at 600 °C. The Nb doped LSCNbx (x = 0.1) perovskite is recommended, considering its high power density and structural stability as an IT-SOFC cathode material.
URI
https://scholarworks.unist.ac.kr/handle/201301/4563
URL
https://pubs.rsc.org/en/Content/ArticleLanding/2014/RA/C4RA02061H#!divAbstract
DOI
10.1039/c4ra02061h
ISSN
2046-2069
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