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- Kwak, Ja Hun
- Molecular Catalysis Lab.
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A common intermediate for N2 formation in enzymes and zeolites: Side-On Cu-nitrosyl complexes
- Author(s)
- Kwak, Jahun, Lee, Jong H., Burton, Sarah D., Lipton, Andrew S., Peden, Charles H. F., Szanyi, Janos
- Issued Date
- 2013-09
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.52, no.38, pp.9985 - 9989
- Abstract
- Side on Combined FTIR and NMR studies revealed the presence of a side-on nitrosyl species in the zeolite Cu-SSZ-13. This intermediate is very similar to those found in nitrite reductase enzyme systems. The identification of this intermediate led to the proposal of a reaction mechanism that is fully consistent with the results of both kinetic and spectroscopic studies.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
- Keyword (Author)
- IR spectroscopy, NMR spectroscopy, reaction mechanisms, reduction, zeolites
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