The 115th General Meeting of the Korean Chemical Society
Abstract
By interpenetrating the structure, the metal-organic frameworks (MOFs) would have advantages in stability and controlling pore sizes. First of all, metal-organic frameworks [Ni(btc)(AP)] having hms topology could be prepared via one-pot de novo synthesis combining Nickel(Ⅱ) nitrate precursor, btc(btc = trimesic acid) and AP(AP = Azopyridine) in mixed solvent. Then by heat treatment in flowing N2 gas condition, the MOFs with hms topology would be interpenetrated and we can confirm this status by several analysis methods.