The 115th General Meeting of the Korean Chemical Society
Abstract
The tuning of status of SBU is one of the challenges for proper target properties in coordination chemistry. The reaction of Zn2+ ion and carboxylate generate Zn4O(COO)6 SBU frequently. Here we examined reactions of Zn(NO3)3●6H2O and H3BTB ligand in DMF and obtained 2-fold interpenetrated structure composed of 3-c BTB ligand and 6-c Zn4O(COO)6 metal cluster, thereby, it is 3,6-c ant net. It is tuned that coordination geometry of Zn4O(COO)6 SBU on synthesized metal-organic frameworks (MOFs) depend on exchanging solvents. We will be discussed analysis of MOFs based on solvent exchange.