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- Lah, Myoung Soo
- Frontier Energy Storage Material Lab.
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Simple and Efficient Regeneration of Metal-Organic Frameworks via Acid-Base Treatment
- Author(s)
- 한승완, Lah, Myoung Soo
- Issued Date
- 2015-10-14
- Fulltext
- https://new.kcsnet.or.kr/?mid=abstract_view&uid=32516&page=14&wordfield=partnum&main_number=116
- Citation
- The 116th General Meeting of the Korean Chemical Society
- Abstract
- Simple and efficient regenerations of MOF-5 and HKUST-1 are demonstrated via acid-base treatment. The reactants are recovered simply dissolving the deteriorated MOFs using a strong acid. The pristine MOFs are regenerated in high yields by adjusting the solution pH either via in-situ base formation or via ex-situ base addition. The both regeneration protocols are environmentally benign and cost effective because the reactants in the deteriorated MOFs are recycled. Especially the ex-situ base addition protocol can be done in a cheap and environmentally friendly ethanol/water mixed solvent at ambient condition and is suitable for large scale batch regeneration owing to the simple procedure and short reaction time.
- Publisher
- Korean Chemical Society
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