The electrons in graphene exhibit unusual two-dimensional behaviors, which can be described by massless Dirac quasiparticles. In order to understand the fundamental electronic properties of graphene, extensive studies have been focused on graphene both experimentally and theoretically. Undoubtedly, however, not only the electronic property of graphene itself but also that of graphene on metallic substrates is of great importance for the further applications. In this study we investigated the scattering behaviors of electrons in single layer graphene (SLG) on a Cu(111) substrate by means of low-temperature scanning tunneling microscopy (LT-STM) and scanning tunneling spectroscopy (STS). When there is a defect in graphene, we can observe the scattering of electrons in the form of interference pattern by STM. In previous STM studies, the energy level of Dirac point has been assigned by the position of a dip in dI/dV curve. It is very difficult, however, to determine the exact position of Dirac point from STS for the graphene on metallic substrates, because surface states of the substrate is too close to Dirac point of graphene in energy level. Here, we could successfully deconvolute and identify the electronic dispersion relations in graphene and in Cu(111) by applying Fourier transformation to one-dimensional and two-dimensional STS maps, which enables us to resolve surface states of Cu(111) and Dirac point of graphene respectively. We will also present our first observation of the defect-induced intravalley scattering, which has not been observed experimentally to date for SLG. Our results show that the careful examination of interference pattern can provide valuable information regarding intravalley, intervalley, and interband scatterings of electrons in graphene/Cu(111).