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Baek, Jong-Beom
Center for Dimension-Controllable Organic Frameworks
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Edge-Selectively Sulfurized Graphene Nanoplatelets as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction: The Electron Spin Effect

Author(s)
Jeon, In-YupZhang, ShengZhang, LipengChoi, Hyun-JungSeo, Jeong-MinXia, ZhenhaiDai, LimingBaek, Jong-Beom
Issued Date
2013-11
DOI
10.1002/adma.201302753
URI
https://scholarworks.unist.ac.kr/handle/201301/3998
Citation
ADVANCED MATERIALS, v.25, no.42, pp.6138 - 6145
Abstract
To replace precious platinum (Pt)-based electrocatalysts for cathodic oxygen reduction reaction (ORR), edge-selectively sulfurized graphene nanoplatelets (SGnP) are synthesized as efficient metal-free electrocatalysts simply by ball-milling pristine graphite in the presence of sulfur (S 8). The resultant SGnPs exhibit remarkable electrocatalytic activity toward ORR with better tolerance to methanol crossover/CO poisoning effects and longer-term stability than those of pristine graphite and commercial Pt/C electrocatalysts. Edge-Selectively Sulfurized Graphene Nanoplatelets as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction: The Electron Spin Effect
Publisher
WILEY-V C H VERLAG GMBH
ISSN
0935-9648
Keyword (Author)
Ball-millingElectrocatalystsGraphene nanoplateletsOxygen reduction reactionSulfurization

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