File Download

There are no files associated with this item.

  • Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
Related Researcher

최원영

Choe, Wonyoung
Laboratory for Sustainable Future
Read More

Views & Downloads

Detailed Information

Cited time in webofscience Cited time in scopus
Metadata Downloads

Evolution of form in metal-organic frameworks

Author(s)
Choe, Wonyoung
Issued Date
2018-03-22
URI
https://scholarworks.unist.ac.kr/handle/201301/37830
Citation
255th ACS National Meeting & Exposition
Abstract
Controlling interior of solid state materials to create various forms, such as core-shell, hollow, matryoshka, york-shell, and multi-shell hollow particles, has been an important challenge for synthetic chemists. In this presentation, we show a synthetic strategy to synthesize single-crystalline double-shell hollow metal-organic framework (MOF) crystals via sequential self-assembly. Such examples of extreme self-assembly might open up new avenues to various forms of MOFs for synthesizing single crystalline multi-shelled hollow MOF with hierarchical porous materials with trimodal (for example, micro-/meso-/macro porous structures) pore system. Further, MOF chemists can design biomimetic catalytic systems similar to native pyruvate dehydrogenase, composed of three different enzymes that are distributed individually in two shells, using the concept of the spatial separation presented here.
Publisher
American Chemical Society

qrcode

Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.