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박종남

Park, Jongnam
Materials and Chemistry Lab.
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Synthesis and characterization of In1-xGaxP@ZnS alloy core-shell type colloidal quantum dots

Author(s)
Joo, JinwhanChoi, YonghoonSuh, Yo-HanLee, Chang-LyoulBae, JoonwonPark, Jongnam
Issued Date
2020-08
DOI
10.1016/j.jiec.2020.03.029
URI
https://scholarworks.unist.ac.kr/handle/201301/36807
Fulltext
https://www.sciencedirect.com/science/article/pii/S1226086X2030157X?via%3Dihub
Citation
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.88, pp.106 - 110
Abstract
We report synthesis of colloidal quantum dots (CQDs), indium gallium phosphide with zinc sulphide shell (In1-xGaxP@ZnS) by a hot injection method and investigate effects of In/Ga ratio on the optical properties of the obtained CQDs. The bandgap of CQDs (1.34-3.54 eV) is controlled by the In/Ga ratio without the quantum confinement effect. The photoluminescence (PL) quantum yield is also dependent on the In/Ga ratio, and temperature dependent PL results show that the randomness of crystal lattice is the most influential parameter. These results show that the In1-xGaxP alloy CQDs can be useful for absorbing the whole range of visible light. In addition, this article can provide background knowledge regarding effect of core metal composition on the optical properties of produced CQDs. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
Publisher
ELSEVIER SCIENCE INC
ISSN
1226-086X
Keyword (Author)
Quantum dotIndium phosphideGallium phosphideAlloy nanoparticles
Keyword
INP/ZNS NANOCRYSTALSCDSEDEVICESGAPINP

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